Castor oil is the fixed oil obtained by cold expression of the seeds of Ricinus communis Linn., belonging to family Euphorbiaceae.
CASTOR OIL
Synonyms
Castor bean oil, castor oil seed, oleum ricini, ricinus oil,
oil of palma christi, cold-drawn castor oil.
Biological Source
Castor oil is the fixed oil obtained by cold expression of
the seeds of Ricinus communis Linn.,
belonging to family Euphorbiaceae.
Geographical Source
It is mainly found in India, Brazil, America, China,
Thai-land; in India it is cultivated in Gujarat, Andhra Pradesh, and Karnataka.
Preparation
Castor oil is obtained from castor seeds. The oil is
obtained by two ways; either after the removal of the seed coat or with the
seed coat. Seed coats are removed by crushing the seeds under the grooved
rollers and then they are subjected to a current of air to blow the testas. The
kernels are fed in oil expellers and at room temperature they are expressed
with 1 to 2 tons pressure per square inch till about 30% oil is obtained. The
oil is filtered, steamed 80–100°C to facilitate the coagulation and precipitation
of poisonous principle ricin, proteins and enzyme lipase present in it. Oil is
then filtered and this oil with 1% acidity is used for medical purpose.
The oil cake which remains contains of ricin, lipase and
about 20% oil. The cake is grounded, steamed to 40° to 80°C, and a pressure of
3 tons pressure per sq. inch is applied. This yields the second quality of oil
with 5% acidity and is used for industrial purpose.
The residual cake which remains after the expression of the
second quality oil still contains about 8 to 10% oil. This oil is obtained by
subjecting it to extraction in soxhlet with lipid solvents. This oil obtained
is also used in industry. The residual cake is used as manure and not fed to animal
due to the presence of ricin. The cake is also used for the production of
lipase.
Characteristics
Medicinal or the first grade or Pale pressed castor oil is
colourless or slightly yellow coloured. It is a viscid liquid which has slight
odour with slightly acrid taste. Castor oil is soluble in absolute alcohol in
all proportions; Specific gravity is 0.958 to 0.969, refractive index at 40°C
is 1.4695 to 1.4730, acid value not more than 2, saponification value 177 to
187, and acetyl value is about 150.
Chemical Constituents
Castor oil consists of glyceride of ricinoleic acid,
isoricinoleic, stearic, and dihydroxy stearic acids. Ricinoleic acid is
responsible for laxative property. Castor oil also contains vitamin F. 90% of
the fatty acid content is ricinoleic acid. The ricinoleic acid is an 18-carbon
acid having a double bond in the 9–10 position and a hydroxyl group on the 12th
carbon. This combination of hydroxyl group and unsaturation occurs only in
castor oil.
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Identification Tests
About 5 ml of light petroleum (50° to 60°) when mixed with
10 ml of castor oil at 15.5° shows a clear solution, but if the amount of light
petroleum is increased to 15 ml, the mixture becomes turbid. This test is not
shown by other oils.
Uses
Castor oil is mild purgative, fungistatic, used as an
ointment base, as plasticizer, wetting agents, as a lubricating agent.
Ricinoleic acid is used in contraceptive creams and jellies; it is also used as
an emollient in the preparation of lipsticks, in tooth formulation, as an ingredient
in hair oil. The dehydrated oil is used in the manufacture of linoleum and
alkyl resin. The main use of castor oil is the industrial production of
coatings, also employed to make pharmaceuticals and cosmetics in the textile
and leather industries and for manufacturing plastics and fibres.
Marketed Products
It is one of the ingredients of the preparations known as
Lip balm and Muscle and joint rub (Himalaya Drug Company).
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